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All spills require a spill response regardless of reportability.
When in doubt, call the reporting line. It is better to be advised your spill is not reportable than to be in violation of the Spill Rule.
Yes, and spills of these individual substances must be reported as do spills of combinations of these substances.
Always report the total amount spilled.
Both of you. Owners and/or operators of facilities and modes of transportation are required to report spills. Reporting the spill in a timely manner is more important than immediately determining fault or responsibility.